
Private expenses from your employees can be paid directly to the employee’s account. Here is how it works.
If your employees make a private expense for the company, you can pay it directly from the bank to the account. You can then book it as a normal expense against the bank.
However, you technically miss the actual transfer from your bank to the employee's - which some accountants or tax people may be unhappy about. So the correct thing to do is to create a short-term liability account for the employee and post to it.
You can always see how much the company owes the employee by going to the balance sheet :